Browsing by Author Walker, Emma J.

Jump to: 0-9 A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
or enter first few letters:  
Showing results 1 to 1 of 1
  • OER000002345.pdf.jpg
  • Journal Article

  • Authors : Walker, Emma J. (2023)

  • Many enzymes display non-Arrhenius behaviour with curved Arrhenius plots in the absence of denaturation. There has been significant debate about the origin of this behaviour and recently the role of the activation heat capacity (Δ𝐶# ‡) has been widely discussed. If enzymecatalysed reactions occur with appreciable negative values of Δ𝐶# ‡ (arising from narrowing of the conformational space along the reaction coordinate), then curved ...